Cheronis, Nicholas Entrikin, John B. Hodnett, Ernest M
Semicro qualitative organic analysis: The systematics identification of organic compounds
- 3 ed
- John Wiley & Sons 1965
- 1060 p. tabls., grafs., ilus.
Identification; the systematic approach; physical methods; microscopic methods; sample size. Equipment and procedures for small-scale work. Fractionation procedures: Crystallization; lation; sublimation; extraction. Fractionation procedures: Chromatographic procedures; other methods fractionations. Physical properties of organic compounds. The separations of mixtures: Mixtures; the use other methods of separation.Preliminary examination of the pure compound; analysis elements. Classifications by solubility.Classifications by the indicator method. Tests for the classification of an unknown: An inventory and a forward look; tests for special classes. Problems in the derivatization of organic compounds. Derivatives of carboxylic acids and acid derivatives: Carboxylic acids; amino acids; acid halides; acid anhydrides. Derivatives of alcohol and phenols monohydric and polyhydric: Alcohols; phenols. Derivatives of aldehydes, ketones, and acetals. Derivatives of carbohydrates. Derivatives of esters and ethers. Derivatives of halogen compounds: Alkyl and cycloalkyl halides; halides; fluorine compounds. Derivatives of hydrocarbons: Alkanes and cycloalkanes; alkenes and cycloalkenes, alkynes, dienes; aromatics hydrocarbons. Derivates of amino-nitrogen function: Amines; hydrazines; amines, imines, and ureas. Derivates of other nitrogen functions: Azo compounds; azoxy and hydrazo compounds; isocyanates and isocyanides; nitriles; nitro compounds; nitroso compounds. Derivates of sulfur functions: Sulfonamides; sulfonyl chlorides; sulfonic acids; thiocyanates and isothiocyanates; thioethers; thiols mercaptans and thiophenols Instrumental methods. Tables of organic compounds with their constants and derivatives; nomenclature.